For one thing, Windows wants to be on the primary master, hda in Linux terms.
A floppy boot disk for Fedora 2 is difficult, as it won't fit. However, you can configure the grub boot loader to make Windows the default. Post your /boot/grub/grub.conf file for the specifics (it's only readable by root).
Here's mine for an example (I have Windows on the primary and Fedora on the slave):
# grub.conf generated by anaconda
# Note that you do not have to rerun grub after making changes to this file
# NOTICE: You have a /boot partition. This means that
# all kernel and initrd paths are relative to /boot/, eg.
# root (hd1,0)
# kernel /vmlinuz-version ro root=/dev/hdb2
# initrd /initrd-version.img
title Fedora Core (2.6.5-1.358)
kernel /vmlinuz-2.6.5-1.358 ro root=LABEL=/ rhgb quiet acpi=on
Notice the Windows entry, it loads the second partition of the first drive.
I would change default=0 to default=1 to boot Windows by default.
for more about grub.conf.